ChansonRolandV6, Main, Exploration, bibRecord, 000C58

Stereospecific Diaza‐Cope Rearrangement Driven by Steric Strain

Identifieur interne : 000C58 ( Main/Exploration ); précédent : 000C57; suivant : 000C59

Stereospecific Diaza‐Cope Rearrangement Driven by Steric Strain

Auteurs : Hyunwoo Kim [Canada] ; Yen Nguyen [Canada] ; Alan Lough [Canada] ; Jik Chin [Canada]

Source :

Angewandte Chemie [ 0044-8249 ] ; 2008-10-27.

RBID : ISTEX:6459DD12AA7CAE57965AEE7F69607AE93098376C

English descriptors

Entity :
- org : Natural Sciences and Engineering Research Council of Canada.
- pers : A. C. Cope, A. Dullin, A. J. Lough, A. Koprianiuk, A. Lee, A. Lough, A. M. M. Castro, A. Ricci, A. Shibahara, Alan J. Lough, B. M. Kim, B. M. Trost, B. T. Vu, C. A. Guyton, C. E. Song, C. Klein, C. Lukacs, C. Mioskowski, C. Palomo, C. Timmons, C. Yen, Computation, D. A. Watson, D. C. Kim, D. Carvajal, D. Lee, D. Lucet, D. S. Chung, D. Savoia, E. A. Liu, E. Doering, E. Goldschmitt, E. J. Corey, E. J. Jeong, E. M. Hardy, E. R. Davidson, F. B. Panosyan, F. Dufrasne, F. E. Ziegler, F. Lux, F. Mancin, F. Podlaski, F. Vögtle, G. Alhakimi, G. B. Bennett, G. Gilli, G. J. Haley, G. Li, G. Seconi, H. Fujii, H. Hopf, H. Kim, H. Park, H. Schönenberger, H. Wrobel, H. Yen, I. Fleming, I. Iwakura, J. A. J. Breuzard, J. Chin, J. Dunogu, J. Engel, J. J. Gajewski, J. Karl, J. Kim, J. M. Aizpurua, J. Med, J. P. Picard, J. Suh, J. W. Reed, K. A. Black, K. B. Simonsen, K. G. Gadamasetti, K. M. Kim, K. N. Houk, K. Niebler, L. A. Paquette, L. Birladeanu, L. Chagal, L. Studnicki, L. T. Vassilev, M. Gelbcke, M. Hatanaka, M. J. S. Dewar, M. Kanai, M. L. Christ-Tommasino, M. Legido, M. Lemaire, M. R. Schneider, M. Shibasaki, N. Fotouhi, N. Fukuda, N. Kong, N. Thavarajah, O. Wiest, P. Gilli, P. M. Deya, P. Mangeney, R. B. Woodward, R. Fan, R. G. Bergman, R. Galarza, R. Gust, S. E. Webber, S. Ham, S. Hong, S. R. S. S. Kotti, S. Roland, S. T. Haeberlin, S. Tanaka, T. Hudlicky, T. Ikeno, T. Kitagawa, T. Le Gall, T. Mita, T. Nagata, T. Spruss, T. Yamada, U. Kammlott, U.S. Patent, V. Bertolasi, V. Ferretti, W. Kim, W. Lennartz, W. Nam, W. R. Roth, Y. Fukuta, Y. Funahashi, Y. Yeung, Z. Filipovic.
- place : Canada, Kokura.
Teeft :
- Angew, Chem, Equilibrium constant, Hydrogen bond, Initial diimines, Kcal, Lough, Mesityl group, Rearrangement, Rearrangement reaction, Sigmatropic, Sigmatropic reaction, Steric, Steric effect, Steric strain, Verlag gmbh.

Abstract

Innere Anspannung: Sterische Spannung führt dazu, dass die gezeigte Diaza‐Cope‐Umlagerung vollständig abläuft, und das laut HPLC an chiraler Phase und Kristallstrukturanalyse hoch stereospezifisch (>99.5 % ee). Die experimentellen und berechneten Werte der Geschwindigkeits‐ und Gleichgewichtskonstanten der Umlagerung stimmen gut miteinander überein.

Url:

https://api.istex.fr/ark:/67375/WNG-W2XWFN59-M/fulltext.pdf

DOI: 10.1002/ange.200801974

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001F40
to stream Istex, to step Curation: 001E01
to stream Istex, to step Checkpoint: 000C05
to stream Main, to step Merge: 000C65
to stream Main, to step Curation: 000C58

Le document en format XML

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<author><name sortKey="Nguyen, Yen" sort="Nguyen, Yen" uniqKey="Nguyen Y" first="Yen" last="Nguyen">Yen Nguyen</name>
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<author><name sortKey="Lough, Alan" sort="Lough, Alan" uniqKey="Lough A" first="Alan" last="Lough">Alan Lough</name>
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<term>T. Nagata</term>
<term>T. Spruss</term>
<term>T. Yamada</term>
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<front><div type="abstract" xml:lang="de">Innere Anspannung: Sterische Spannung führt dazu, dass die gezeigte Diaza‐Cope‐Umlagerung vollständig abläuft, und das laut HPLC an chiraler Phase und Kristallstrukturanalyse hoch stereospezifisch (>99.5 % ee). Die experimentellen und berechneten Werte der Geschwindigkeits‐ und Gleichgewichtskonstanten der Umlagerung stimmen gut miteinander überein.</div>
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Serveur d'exploration Chanson de Roland (version 6)

Stereospecific Diaza‐Cope Rearrangement Driven by Steric Strain

Stereospecific Diaza‐Cope Rearrangement Driven by Steric Strain

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri